Especiales Tecnociencia  
Diciembre 2002
Especial Residuos
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Bibliografia
epígrafe Residuos orgánicos
  • Held, C., Wellacher, M. Robra, K.H. , Gubitz, G.M.
    Two-stage anaerobic fermentation of organic waste in CSTR and UFAF-reactors.
    Info Bioresource technology.Jan 2002. v. 81 (1)
    p. 19-24.
    The mechanically separated liquid fraction of organic waste from households was used as a substrate for anaerobic fermentation. A two-step system consisting of a 200 l continuously stirred tank reactor (CSTR) and a 50 l upflow anaerobic filter filled with glass foam pearls was constructed. The CSTR was operated for 5 months with a loading rate of 9.8 kg CSB m(-3) day(-1). At a resulting hydraulic retention time (HRT) of 24 days, 68% COD was degraded and a gas productivity of 4.0 m3 m(-3) day(-1) was achieved. Further digestion of the CSTR output was separately optimised in a 20 l-UFAF and based on these results a 50 l-UFAF was connected to the CSTR. At a resulting hydraulic retention time (HRT) of 6 days 38% COD was degraded and a gas productivity of 1.8 m3 m(-3) day(-1) was achieved with the 50 l-UFAF. Thus, the overall degradation efficiency of the two-phase system was 80%. The methane content (61%) of the biogas produced in the 50 l-UFAF was higher than that for the CSTR (47%). The effluent from the second stage of the two-phase system was odourless and could thus be re-used in the composting process.

  • Chen, C.C., Lin, C.Y. , Lin, M.C.
    Acid-base enrichment enhances anaerobic hydrogen production process.
    Info Applied microbiology and biotechnology.Feb 2002. v. 58 (2)
    p. 224-228.
    This study offers a novel and quick enrichment technology that can be used as a preliminary method to obtain a hydrogen-producing species from the biological sludge produced by wastewater treatment. The influences of acid-base enrichment (by sludge pH adjustment) on the anaerobic hydrogen-producing microorganisms were investigated using serum bottle assays. The enrichment pH values were controlled at 3, 4, 5, 7, 10, 11 and 12 with 1 N hydrochloric acid and 1 N sodium hydroxide. For each enrichment pH, the cultivation pH values were controlled at 5, 6 and 7. Based on the experimental results, hydrogen accumulation from sludge with acid or base enrichment is higher than that of the control. The hydrogen-production potential of the sludge with acid or base enrichment is 200 and 333 times enhanced, compared with the control, when the enrichment pH is 10 and 3, respectively. The enhancement is due to a shortening of the micro-organisms' lag-time which occurs at a proper cultivation-pH level.

  • Lopez, M.J. , Elorrieta, M.A., Vargas-Garcia, M.C. , Suarez-Estrella, F. Moreno, J.
    The effect of aeration on the biotransformation of lignocellulosic wastes by white-rot fungi.
    Info Bioresource technology.Jan 2002. v. 81 (2)
    p. 123-129.
    The mineralisation and the humification of organic matter (OM) in sterile horticultural plant wastes inoculated with Coriolus versicolor or Phanerochaete flavido-alba was investigated under different aeration rates in order to determine their efficacy as potential inoculants for composting. The change in elemental composition, lignin content and OM fractions was analysed during a 90-day incubation. Both fungi degraded 30% of lignin at low aeration rates. Different aeration rates led to significant changes in OM mineralisation induced by C. versicolor, but did not have noticeable effect on P. flavido-alba activity. The mineralisation was more effectively carried out by P. flavido-alba than by C. versicolor. Lignin degradation and the linked humification process were equally achieved by the two fungi and were enhanced in aerated conditions. The fungi analysed may facilitate the composting of lignocellulosic wastes by means of an increase in substrate bioavailability and OM humification.

  • Pascual, J.A. , Moreno, J.L. , Hernandez, T., Garcia, C.
    Persistence of immobilised and total urease and phosphatase activities in a soil amended with organic wastes.
    Source Info Bioresource technology.Mar 2002. v. 82 (1)
    p. 73-78.
    This paper reports on the persistence of total and immobilised enzyme activities (urease and phosphatase) in a soil amended with organic wastes containing high levels of total-urease and phosphatase activity. Fresh organic materials showed the highest values for both total-enzymatic activities. The addition of organic waste to soil increased both total-enzymatic activities in the soil, which, after 360 days, showed values above those of the control. Immobilised enzymes were also higher in the fresh wastes than in the soil with compost, while the specific enzymatic activity levels (enzymatic activity per unit of carbon) were similar. The immobilised urease activity was greater in the amended soil than in the control. At the beginning of the incubation period, the immobilised urease activity was significantly higher in the soil amended with fresh organic wastes than with compost. However, this activity decreased with incubation, whilst the compost-immobilised urease activity increased with time. The effect of organic amendment on immobilised phosphatase activity was similar to that shown by immobilised urease but less pronounced. The persistence of both enzymes was significantly higher in the soil amended with compost than in that amended with fresh materials.

  • Salminen, E. , Rintala, J.
    Anaerobic digestion of organic solid poultry slaughterhouse waste--a review.
    Info Bioresource technology.May 2002. v. 83 (1)
    p. 13-26.
    This work reviews the potential of anaerobic digestion for material recovery and energy production from poultry slaughtering by-products and wastes. First, we describe and quantify organic solid by-products and wastes produced in poultry farming and poultry slaughterhouses and discuss their recovery and disposal options. Then we review certain fundamental aspects of anaerobic digestion considered important for the digestion of solid slaughterhouse wastes. Finally, we present an overview of the future potential and current experience of the anaerobic digestion treatment of these materials.

  • Anikwe, M.A.N.
    Long term effect of municipal waste disposal on soil properties and productivity of sites used for urban agriculture in Abakaliki, Nigeria.
    Info Bioresource technology.July 2002. v. 83 (3)
    An assessment on the impact of long term (20 years) municipal waste disposal on soil physicochemical properties and soil productivity in municipal waste dump sites was carried out in urban Abakaliki, southeastern Nigeria. Profile pits were dug at selected points and auger and core samples were collected from different soil horizons of dump and non-dump sites using free survey technique to choose observation points. There were differences in particle size distribution between dump and non-dump sites. Similarly, soil bulk density was lower by 9-13% while total porosity and hydraulic conductivity were higher by 9-14% and 240-463%, respectively, in the dump site relative to non-dump sites. Soil organic matter, total nitrogen, cation exchange capacity (CEC) and percent base saturation increased from 701 to 743, 646 to 740, 7% to 10% and 5% to 14%, respectively, in the dump site soil relative to non-dump site soil. These results were confirmed by a high coefficient of alienation (degree of unrelatedness,) in bulk density, 0.65; total porosity, 0.58; hydraulic conductivity, 0.87; organic matter, 0.93; total N, 0.82; pH, 0.85 and cation exchange capacity, 0.97 between dump and non-dump soils. Heavy metals (Pb, Cu, Fe and Zn) increased by between 214% and 2040% in dump site soils relative to non-dump site soil. This may lead to increased uptake of metals by some test crops although their transfer ratios differ from crop to crop. Long term dumping of municipal wastes can influence soil properties and productivity at municipal waste dump sites but still may be used for farming provided that ecotoxological risks associated with its usage are continuously assessed and controlled.

  • Orlando, U.S., Baes, A.U., Nishijima, W., Okada, M.
    A new procedure to produce lignocellulosic anion exchangers from agricultural waste materials.
    Info Bioresource technology.July 2002. v. 83 (3)
    p. 195-198.
    Two lignocellulosic agricultural waste materials (LCM), sugarcane bagasse (BG) and rice hull (RH), were converted into weak-base anion exchanger and evaluated for their exchanger capacity for nitrate. Pure cellulose (PC) and pure alkaline lignin (PL) were also used as reference materials to elucidate possible reactivity in LCM. Epoxy and amino groups were introduced into BG, RH, PC and PL substrates after the reaction with epichlorohydrin and dimethylamine in the presence of pyridine and an organic solvent N,N-dimethylformamide (DMF). Amino group incorporation into cellulose decreased with the presence of water in the reaction mixture and increased with the reaction time and presence of a catalyst (pyridine). The highest maximum nitrate exchange capacity (Qmax) and yields of the prepared exchangers was obtained from PL (1.8 mmol g-1 and 412.5%), followed by BG (1.41 mmol g-1 and 300%), PC (1.34 mmol g-1 and 166%) and RH (1.32 mmol g-1 and 180%). The proposed synthetic procedure was effective in modifying PL, PC and LCM chemically resulting in a higher yield and nitrate removal capacity.

  • Guardia, A. de.,Brunet, S., Rogeau, D., Matejka, G.
    Fractionation and characterisation of dissolved organic matter from composting green wastes.
    Info Bioresource technology.July 2002. v. 83 (3)
    p. 181-187.
    A new fractionation procedure using membrane ultrafiltration (UF), followed by chemical characterisation - measurement of total organic carbon (TOC), chemical oxygen demand (COD) and organic nitrogen and spectroscopic study - was applied to aqueous extracts of composting green wastes. Three membranes of molecular weight (MW) cut-offs of 1, 10 and 100 kDa were used. The study demonstrated the first step of the transfer of organic matter from the solids to the aqueous biofilm surrounding the solids. The microbiological consumption of the dissolved organic matter mainly used molecules smaller than 1 kDa, while the aromatisation of the organic matter, observed after 100 days composting, involved molecules larger than 10 kDa.

  • McKendry, P.
    Energy production from biomass. 1. Overview of biomass.
    Info Bioresource technology.May 2002. v. 83 (1)
    p. 37-46.
    The use of renewable energy sources is becoming increasingly necessary, if we are to achieve the changes required to address the impacts of global warming. Biomass is the most common form of renewable energy, widely used in the third world but until recently, less so in the Western world. Latterly much attention has been focused on identifying suitable biomass species, which can provide high-energy outputs, to replace conventional fossil fuel energy sources. The type of biomass required is largely determined by the energy conversion process and the form in which the energy is required. In the first of three papers, the background to biomass production (in a European climate) and plant properties is examined. In the second paper, energy conversion technologies are reviewed, with emphasis on the production of a gaseous fuel to supplement the gas derived from the landfilling of organic wastes (landfill gas) and used in gas engines to generate electricity. The potential of a restored landfill site to act as a biomass source, providing fuel to supplement landfill gas-fuelled power stations, is examined, together with a comparison of the economics of power production from purpose-grown biomass versus waste-biomass. The third paper considers particular gasification technologies and their potential for biomass gasification.

epígrafe Residuos industriales
  • Dewulf, J.P., Langenhove, H.R. van.
    Quantitative assessment of solid waste treatment systems in the industrial ecology perspective by exergy analysis.
    Environmental science & technology.Environmental science & technology (Easton, Pa.)Mar 1, 2002. v. 36 (5)
    Pages p. 1130-1135.

  • Adhvaryu, A., Erhan, S.Z.
    Epoxidized soybean oil as a potential source of high-temperature lubricants.
    Industrial crops and products.May 2002. v. 15 (3)
    Pages p. 247-254.
    Abstract Development and application of biocompatible lubricants are increasing daily as a result of stringent regulations imposed on mineral oil-based lubricants with their non-biodegradable toxic wastes. Before consumer acceptance of vegetable oil-based lubricants, they must overcome certain poor performance characteristics such as thermal and oxidative instabilities. This work demonstrates the improved performance of epoxidized soybean oil (ESBO) over soybean oil (SBO) and genetically modified high oleic soybean oil (HOSBO) in certain high temperature lubricant application. We validated the thermal and deposit forming tendencies of these oils using micro-oxidation and differential scanning calorimetry in conjunction with identification of oxidized products by infrared spectroscopy and also discussed the function of a phenolic antioxidant in these oils. Boundary lubrication properties under high load and low speed were determined and the variations explained based on the structural differences of these vegetable oils.

  • Slavikova, E., Kosikova, B., Mikulasova, M.
    Biotransformation of waste lignin products by the soil-inhabiting yeast Trichosporon pullulans.
    Canadian journal of microbiology.Mar 2002. v. 48 (3)
    Pages p. 200-203.

  • Jagadeeswaran, R, Singaram, P. ,Murugappan, V. .
    Industrial waste ferrogypsum--a substitute for gypsum to alleviate sodicity.
    Australian journal of experimental agriculture.2002. v. 42 (3) (ABBREV TITLE = Aust. j. exp. agric.)
    Pages p. 309-313.
    Note In the special issue: Sodicity issues in agricultural industries--Current research and future directions. Paper presented at a conference held February 28-March 1,2000, Tatura, Victoria, Australia.

  • Chakraborty, N., Sarkar, G.M., Lahiri, S.C.
    Biomethanation of a cellulose-based substrate in the presence and absence of a cellulolytic bacterium.
    World journal of microbiology & biotechnology.June 2002. v. 18 (4)
    Pages p. 321-324.

  • Schuhmacher, M., Rodriguez-Larena, M.C., Agramunt, M.C., Diaz-Ferrero, J., Domingo, J.L.
    Environmental impact of a new hazardous waste incinerator in Catalonia, Spain: PCDD/PCDF levels in herbage samples.
    Chemosphere.July 2002. v. 48 (2)
    Pages p. 187-193.

  • Dias, A.C.P. Fernandes, P., Cabral, J.M.S. ,Pinheiro, H.M.
    Isolation of a biodegradable sterol-rich fraction from industrial wastes.
    Bioresource technology.May 2002. v. 82 (3)
    Pages p. 253-260.
    Several industrial waste materials were screened for their sterol content. The possibility of using these industrial by-products as sterol sources for the microbiological production of 4-androsten-3,17-dione (AD) and 1,4-androsta-diene-3,17-dione (ADD) was investigated. Two methods of obtaining the sterol fraction from wastes were developed. Sterol-rich (96-98%) fractions were isolated in a yield above 70%, from a tall-oil effluent of a paper pulp industry and from edible-oil deodorizates. These fractions were subsequently used as a substrate for microbial degradation by a Mycobacterium sp. strain and proved to be easily converted to AD and ADD.

epígrafe Residuos peligrosos
  • Leenheer, J.A. Hsu, J., Barber, L.B.
    Transport and fate of organic wastes in groundwater at the Stringfellow hazardous waste disposal site, southern California.
    Journal of contaminant hydrology.Oct 2001. v. 51 (3/4)
    Pages p. 163-178.

  • Pollumaa, L. Other Author Maloveryan, A., Trapido, M,. Sillak, H., Author Kahru, A.
    Study of the environmental hazard caused by the oil shale industry solid waste.
    Alternatives to laboratory animals : ATLA.May/June 2001. v. 29 (3)
    Pages p. 259-267.
    The environmental hazard was studied of eight soil and solid waste samples originating from a region of Estonia heavily polluted by the oil shale industry. The samples were contaminated mainly with oil products (up to 7231 mg/kg) and polycyclic aromatic hydrocarbons (PAHs; up to 434 mg/kg). Concentrations of heavy metals and water-extractable phenols were low. The toxicities of the aqueous extracts of solid-phase samples were evaluated by using a battery of Toxkit tests (involving crustaceans, protozoa, rotifers and algae). Waste rock and fresh semi-coke were classified as of "high acute toxic hazard", whereas aged semi-coke and most of the polluted soils were classified as of "acute toxic hazard". Analysis of the soil slurries by using the photobacterial solid-phase flash assay showed the presence of particle-bound toxicity in most samples. In the case of four samples out of the eight, chemical and toxicological evaluations both showed that the levels of PAHs, oil products or both exceeded their respective permitted limit values for the living zone (20 mg PAHs/kg and 500 mg oil products/kg); the toxicity tests showed a toxic hazard. However, in the case of three samples, the chemical and toxicological hazard predictions differed markedly: polluted soil from the Erra River bank contained 2334 mg oil/kg, but did not show any water-extractable toxicity. In contrast, spent rock and aged semi-coke that contained none of the pollutants in hazardous concentrations, showed adverse effects in toxicity tests. The environmental hazard of solid waste deposits from the oil shale industry needs further assessment.

  • Guerrin, F.
    MAGMA: a simulation model to help manage animal wastes at the farm level.
    Computers and electronics in agriculture.Dec 2001. v. 33 (1)
    Pages p. 35-54.
    Abstract MAGMA is a hybrid dynamical system (HDS; i.e. with both continuous and discrete-valued variables) allowing the simulation of management of various kinds of animal manure or slurry production and utilization modes (waste spreading on cultivated crops and fallow land and compost making) It can support decision-making to help better manage such potentially hazardous organic matter (OM) at the farm level with the aims of environmental risk minimization, agricultural efficiency and farming sustainability. One can define several scenarios based on farm structural parameters in MAGMA, for example, animal and crop production characteristics, capacity of manure or slurry spreading equipment, and distances. Each scenario can be tailored according to several management strategies by using switch constants. This paper describes the core of the model, enabling the simulation and scheduling of actions (crop harvest, manure or slurry spreading, etc.) that consume those wastes according to various uses. The use of the model in simulation is explained and a detailed example is given on how it can contribute in choosing alternative management strategies.

  • Sauer, B., Franklin, W., Miner, R., Word, D., Upton, B.
    Environmental tradeoffs: life cycle approach to evaluate the burdens and benefits of emission control systems in the wood panel industry.
    Forest products journal.Mar 2002. v. 52 (3)
    Pages p. 50-59.
    This life cycle inventory was conducted for the American Forest & Paper Association in order to develop a more complete picture of the burdens associated with various emission control technologies currently used in the wood products industry. Control technologies evaluated included biofilters, regenerative thermal oxidation units (RTOs), and regenerative catalytic oxidation units. The control technologies are used to reduce emissions of volatile organic compounds (VOCs) and hazardous air pollutants (HAPs) from press and dryer exhaust streams at plants producing a variety of wood products. If the evaluation of emissions control systems is limited to an evaluation of their efficiency in controlling on-site emissions, significant on- and off-site environmental burdens associated with the operation of control systems can be overlooked. The study found that employing a systems approach to evaluate the emission control technologies clearly identifies the trade-offs involved in controlling VOC and HAP emissions from panel plant press and dryer vents. The control technologies under consideration reduce life cycle HAP and particulate emissions and, in most cases, VOC emissions. These on-site reductions come at the expense of higher energy consumption and associated increases in life cycle emissions of nitrogen oxides, sulfur oxides, greenhouse gases, and solid waste, as well as a variety of fossil fuel combustion-related HAPs including hydrochloric acid, hydrofluoric acid, and mercury. Projections of the effects on energy, greenhouse gases, and VOC and HAP emissions are made based on the use of RTO technology to control panel plant emissions industry-wide.

  • Schuhmacher, M., Rodriguez-Larena, M.C., Agramunt, M.C., Diaz-Ferrero, J., Domingo, J.L.
    Environmental impact of a new hazardous waste incinerator in Catalonia, Spain: PCDD/PCDF levels in herbage samples.
    Chemosphere.July 2002. v. 48 (2)
    Pages p. 187-193.

epígrafe Proyectos europeos
  • RECBUILD Advanced Building materials obtained by Recycling toxic wastes and fly ashes
    Category: Project
    Programme: BRITE/EURAM 2

  • CHEM Chemical Emergency Management decision support system
    Category: Other
    Programme: JRC-ENVPROT 5C
    Extract: Developed by JRC to identify the levels of threat related to the most common types of accidents involving polychlorinated biphenyls (PCB's) and other toxic compounds contained in soot, incinerator fly ash, polluted soils and industrial wastes....

  • PETRA Plant for Evaluating and Testing of Radioactive waste management Alternatives
    Category: Facility
    Programme: JRC-RADWASTE 6C
    Extract: Facility at JRC-Ispra designed to simulate the handling of high-level and medium-level radioactive wastes and to devise treatments for waste that are safer and cheaper. Consists of three 'hot cells', or processing areas for highly radioactive materials, areas for decontamination, a pool for storing waste, and a 'hot' workshop....

  • ECOGYPS Manufacture of a high capacity, acoustic absorption new material, based on phospho-Gypsum and casting sands wastes
    Category: Project
    Programme: CRAFT

  • TRIREPACK Recovery Recycling and Reuse of Packaging materials from post consumer wastes
    Category: Project
    Programme: BRITE/EURAM 2

  • TAC Torus Access Cabin
    Category: Other
    Extract: The Waste Management Group of the JRC is responsible for provision of facilities in support of interventions and shutdowns, respiratory protection equipment and disposal of radioactive and beryllium wastes. This includes also the Torus Access Cabin, which enables personnel to access the JET vessel in a manner which prevents the spread of radioactive contamination beyond controlled areas....

  • BACCHUS Backfilling Control experiment for High level wastes in Underground Storage
    Category: Project
    Programme: RADWASTOM 4C

  • AD-NETT Anaerob Digestion of agro-industrial wastes - information Network
    Category: Project
    Programme: FAIR

  • SIDWASTE Separation and Immobilization of Drilling Wastes
    Category: Project
    Programme: NNE-THERMIE C

  • SURE-PLAST Development of multipurpose industrial units for recycling of plastic wastes by on-line pattern recognition of polymer features
    Category: Project
    Programme: BRITE/EURAM 3

  • VAWAFO Valorisation of Wastes from Food Origin
    Category: Project
    Programme: ENV 2C

  • INTELLTHERMCONTROL
    Category: Project
    Programme: LIFE QUALITY
    Extract: Project acronym is not derived from project title, which is: Enhanced, intelligent processing of food and related wastes using thermophilic populations....

  • ENVIMAN ENV Ironmental MANagement of hazardous mining wastes and effluents
    Category: Project
    Programme: INCO 2

  • WATER BIOREMEDIATION Development of environmentally benign, sustainable industrial technologies for the remediation of industrial wastes and petrochemicals contaminated sites using newly isolated and designed microorganisms.
    Category: Project
    Programme: INCO 2

  • MIAB Enhanced, Intelligent Processing of Food and Related Wastes using Thermophilic Populations
    Category: Project
    Programme: LIFE QUALITY

  • PHEAWAST PHEnolic more ecologicAl resins. Development of control and reuse new systems in prepereg manufacture, avoiding WASTEs
    Category: Project
    Programme: GROWTH

  • WASWAX Waxes from fruit wastes
    Category: Project
    Programme: FAIR

  • COMPAS COMParison of Alternative waste management Strategies for long-lived radioactive wastes
    Category: Project
    Programme: FP5-EAECTP C

  • RECOVEG REcycling horticultural wastes to produce pathogen suppressant COmposts for sustainable VEGetable crop production
    Category: Project
    Programme: LIFE QUALITY

  • WASSERGLASS WASSERGLASS in leather production (in order to minimize tannery wastes)
    Category: Project
    Programme: GROWTH
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